Bond villain Franz Sanchez (Robert Davi) wears a pair of black Ray-Ban Wayfarer II sunglasses in the movie Licence To Kill (1989) and Felix Leiter (Jeffrey Wright) might wear a pair in No Time To Die (2020).
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In the movie Die Another Day (2002), Miranda Frost (played by Rosamund Pike) wears a pair of black Ray-Ban RB4122 sunglasses.